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Hydrogen can be readily used in spark-ignition engines as a clean alternative to fossil fuels. However, a larger burning velocity and a shorter quenching distance for hydrogen as compared with hydrocarbons bring a larger cooling loss from burning gas to the combustion-chamber wall. Because of the large cooling loss, the thermal efficiency of a hydrogen-fueled engine is sometimes lower than that of a conventionally fueled engine. Therefore, the reduction of the cooling loss is very important for improving the thermal efficiency in hydrogen-combustion engines. On the other hand, the direct-injection stratified charge can suppress knocking in spark-ignition engines at near stoichiometric overall mixture conditions. Because this is attributed to a leaner end gas, the stratification can lead to a lowered temperature of burning gas around the wall and a reduced cooling loss.

A thermodynamic based cycle simulation which uses a thermal boundary layer, either, a fully mixed or layered adiabatic core, and a crevice combustion inefficiency routine has been used to explore the sensitivity of NO concentration predictions to critical physical modeling assumptions. An experimental database, which included measurements of residual gas fraction, was obtained from a 2.0 liter Nissan engine while firing on propane. A model calibration methodology was developed to ensure accurate predictions of in-cylinder pressure and burned gas temperature. Comparisons with experimental NO data then showed that accounting for temperature stratification during combustion with a layered adiabatic core and including a crevice/combustion inefficiency routine, improved the match of modeling predictions to data, in comparison to a fully mixed adiabatic core.

Two-stage hybrid combustion for a 6-stroke gasoline direct injection SI engine is a new strategy to control the ignition of the HCCI combustion using hot-burned gas from the stratified lean SI combustion. This combustion is achieved by changing the camshafts, the cam-driven gear ratio and the engine control of a conventional 4-stroke gasoline direct injection engine without using a higher compression ratio, any fuel additives and induction air heating devices. The combustion processes are performed twice in one cycle. After the gas exchange process, the stratified ultra-lean SI combustion is performed. The hot-burned gas generated from this SI combustion is used as a trigger for the next HCCI combustion. After gasoline is injected in the burned gas, the hot and homogeneous lean mixture is recompressed without opening the exhaust valves. Thus the HCCI combustion occurs.

A novel leanburn concept, ‘Barrel-Stratification’ is proposed. Fuel is introduced into the cylinder through one of the intake ports of a dual-intake-valve engine of which the tumbling air motion is intensified by the sophisticated intake port design. Because the velocity component in the direction parallel to the axis of tumble is small, charge stratification realized during the intake stroke is maintained until the end of the compression stroke. By the effects of charge stratification and the turbulence enhancement by tumble, stable combustion is realized even at extremely lean conditions. The concept was verified by flow field analysis applying a multi-color laser sheet technique and the flame structure analysis employing the blue-end image intensification realized by the interference mirror and the short delay phosphor.

Both NOx and unburned HC were reduced by changing the direction of the flame propagation. It is generally said that the optimum ignition position of spark ignition engine is in the center of combustion chamber. However by igniting arround the chamber and propagating the flame toward the center, a smooth heat release pattern due to the decrease in the flame area and a decrease in the unburned gas entering the ring crevise can be anticipated. These effects of this combustion process, which was named the surrounding combustion process (SCP), were experimntally confirmed using the constant volume combustion vessels and the spark ignition engine equipped with six spark plugs per cylinder. Next, the steps for decreasing the number of ignitions TCre considered, and additional three spark plugs for SCP were installed in the four valve pentroof combustion chamber. With this engine, the NOx reduction and the capability of SCP to further improve the lean burn engine fuel economy were confirmed.

Ethanol and acetaldehyde emissions from a direct ignition spark ignition were measured using mass spectrometry. Previous methods focused on eliminating or minimizing interference from exhaust species with identical atomic mass and fragment ions created in ionization process. This paper describes a new technique which exploits the fragment ions from ethanol and acetaldehyde. A survey of mass spectra of all major species of exhaust gas was conducted. It was found that ethanol contributes most ions in mass number 31 and that no other gas species produces ions at this mass number. Acetaldehyde detection suffers more interference. Nevertheless, it was estimated that detection at mass number 43 is possible with 10% error from 2-methylbutane. This new technique was validated in an engine experiment. By running the engine with pure gasoline and E85, the validity of the technique can be checked.

The performance of an extended stroke spark ignition engine has been assessed by cycle simulation. The base engine is a modern turbo-charged 4-stroke passenger car spark-ignition engine with 10:1 compression ratio. A complex crank mechanism is used so that the intake stroke remains the same while the expansion-to-intake stroke ratio (SR) is varied by changing the crank geometry. The study is limited to the thermodynamic aspect of the extended stroke; the changes in friction, combustion characteristic, and other factors are not included. When the combustion is not knock limited, an efficiency gain of more than 10 percent is obtained for SR = 1.5. At low load, however, there is an efficiency lost due to over-expansion. At the same NIMEP, the extended stroke renders the engine more resistant to knock. At SR of 1.8, the engine is free from knock up to 14 bar NIMEP at 2000 rpm. Under knocking condition, the required spark retard to prevent knocking is less with the extended stroke.

An experimental study was performed in a firing SI engine at conditions representative of the warmup phase of operation in which liquid gasoline films were established at various locations in the combustion chamber and the resulting impact on hydrocarbon emissions was assessed. Unique about this study was that it combined, in a firing engine environment, direct visual observation of the liquid fuel films, measurements of the temperatures these films were subjected to, and the determination from gas analyzers of burned and unburned fuel quantities exiting the combustion chamber - all with cycle-level resolution or better. A means of deducing the exhaust hydrocarbon emissions that were due to the liquid fuel films in the combustion chamber was developed. An increase in exhaust hydrocarbon emissions was always observed with liquid fuel films present in the combustion chamber.

The residual gas fraction prior to ignition at the vicinity of the spark plug in a single cylinder, two-valve spark ignition engine was measured with a fast-response flame ionization hydrocarbon detector. The technique in using such an instrument is reported. The measurements were made as a function of the intake manifold pressure, engine speed and intake/exhaust valve-overlap duration. Both the mean level of the residual fraction and the statistics of the cycle-to-cycle variations were obtained.

The prediction of knock onset in spark-ignition engines requires a chemical model for the autoignition of the hydrocarbon fuel-air mixture, and a description of the unburned end-gas thermal state. Previous studies have shown that a reduced chemistry model developed by Keck et al. adequately predicts the initiation of autoignition. However, the combined effects of heat transfer and compression on the state of the end gas have not been thoroughly investigated. The importance of end-gas heat transfer was studied with the objective of improving the ability of our knock model to predict knock onset over a wide range of engine conditions. This was achieved through changing the thermal environment of the end gas by either varying the inlet air temperature or the coolant temperature. Results show that there is significant heating of the in-cylinder charge during intake and a substantial part of the compression process.

A single-zone burn-rate analysis based on measured cylinder pressure data proposed by Gatowski et al. in 1984 was evaluated over the full load and speed range of a spark-ignition engine. The analysis, which determines the fuel mass burning rate based on the First Law of Thermodynamics, includes sub-models for the effects of residual fraction, heat transfer, and crevices. Each of these sub-models was assessed and calibrated. Cylinder pressure data over the full engine operating range obtained from two different engines were used to examine the robustness of the analysis. The sensitivity of predictions to the parameters wall temperature, heat transfer model coefficients and exponent, swirl ratio, motoring polytropic constant, in-cylinder mass, and to uncertainty in pressure data was evaluated.

This paper provides an overview of spark-ignition engine unburned hydrocarbon emissions mechanisms, and then uses this framework to relate measured engine-out hydrocarbon emission levels to the processes within the engine from which they result. Typically, spark-ignition engine-out HC levels are 1.5 to 2 percent of the gasoline fuel flow into the engine; about half this amount is unburned fuel and half is partially reacted fuel components. The different mechanisms by which hydrocarbons in the gasoline escape burning during the normal engine combustion process are described and approximately quantified. The in-cylinder oxidation of these HC during the expansion and exhaust processes, the fraction which exit the cylinder, and the fraction oxidized in the exhaust port and manifold are also estimated.

The 4-stroke SI engine offers better performance if its valve events can be varied depending on the operating conditions. Some engines in production are therefore incorporated with variable valve timing (VVT) mechanisms. All of such mechanisms available today however are for two-mode change-over between low-and high-speed operations. To achieve even better output and fuel economy, a new multi-mode VVT mechanism has been developed, featured by a unique hydraulic device for three-mode change-over as follows: Deactivate both intake and exhaust valves Select low-speed cam with moderate lifts and short durations Select high-speed cam with high lifts and long durations This mechanism enables shutting off unnecessary cylinders during low-speed cruise, or select optimum valve events during WOT acceleration over the entire engine speed range.

The chemistry of unburned hydrocarbon oxidation in SI engine exhaust was modeled as a function of temperature and concentration of unburned gas for lean and rich mixtures. Detailed chemical kinetic mechanisms were used to model isothermal reactions of unburned fuel/air mixture in an environment of burned gases at atmospheric pressure. Simulations were performed using five pure fuels (methane, ethane, propane, n-butane and toluene) for which chemical kinetic mechanisms and steady state hydrocarbon (HC) emissions data were available. A correlation is seen between reaction rates and HC emissions for different fuels. Calculated relative amounts of intermediate oxidation products are shown to be consistent with experimental measurements.

A method for determining the flame contour based on the flame arrival time at the fiber optic (FO) spark plug and at the head gasket ionization probe (IP) locations has been developed. The experimental data were generated in a single-cylinder Ricardo Hydra spark-ignition engine. The head gasket IP, constructed from a double-sided copper-clad circuit board, detects the flame arrival time at eight equally spaced locations at the top of the cylinder liner. Three other IP's were also installed in the cylinder head to provide additional intermediate data on flame location and arrival time. The FO spark plug consists of a standard spark plug with eight symmetrically spaced optical fibers located in the ground casing of the plug. The cylinder pressure was recorded simultaneously with the eleven IP signals and the eight optical signals using a high-speed PC-based data acquisition system.

This paper uses a model which calculates the flame kernel formation and its early development in spark ignition engines to examine the causes of cycle-to-cycle combustion variations. The model takes into account the primary physical factors influencing flame development. The spark-generated flame kernel size and temperature required to initialize the computation are completely determined by the breakdown energy and the heat conduction from burned region to unburned region. In order to verify the model, the computation results are compared with high-speed Schlieren photography flame development data from an operating spark-ignition engine; they match remarkably well with each other at all test conditions. For the application of this model to the study of cycle-to-cycle variation of the early stage of combustion, additional input is required.

In order to control the mixture formation, a mixture injected 4-valve SI engine was developed with a small mixture chamber and mechanically driven mixture injection valve installed into the cylinder head. The mixture injection valve was located at the center of the combustion chamber. The mixture was injected from the final stage of the intake stroke to the beginning of the compression stroke. The mixture distribution and in-cylinder flow field inside the combustion chamber were measured by a pair of laser two-dimensional visualization techniques. A planar-laser-induced exciplex fluorescence technique was used to visualize the in-cylinder mixture formation by obtaining spectrally separated fluorescence images of liquid and vapor phase fuel distribution. Particle image velocimetry (PIV) was used to obtain flow field images. In the case of the mixture injected SI engine, the mixture injected into the swirl center was retained during the compression stroke.

The effect of engine operating parameters (speed, spark timing, and fuel-air equivalence ratio [Φ]) on hydrocarbon (HC) oxidation within the cylinder and exhaust system is examined using propane or isooctane fuel. Quench gas (CO2) is introduced at two locations in the exhaust system (exhaust valve or port exit) to stop the oxidation process. Increasing the speed from 1500 to 2500 RPM at MBT spark timing decreases the total, cylinder-exit HC emissions by ∼50% while oxidation in the exhaust system remains at 40% for both fuels. For propane fuel at 1500 rpm, increasing Φ from 0.9 (fuel lean) to 1.1 (fuel rich) reduces oxidation in the exhaust system from 42% to 26%; at 2500 RPM, exhaust system oxidation decreases from 40% to approximately 0% for Φ = 0.9 and 1.1, respectively. Retarded spark increases oxidation in the cylinder and exhaust system for both fuels. Decreases in total HC emissions are accompanied by increased olefinic content and atmospheric reactivity.

A large quantity of recirculated exhaust gas is used to reduce NOx emissions and improve fuel economy at the same time. The effect of exhaust gas recirculation (EGR) was investigated under the stoichiometric and lean operating conditions and compared with the effect of lean operation without EGR. A mixture injected SI engine that has a mechanically driven mixture injection valve installed was prepared. In this engine, it is possible to charge combustible mixture independently from combustion air and recirculated exhaust gas introduced from intake port in order to stratify the mixture. The effect of the EGR ratio on NOx emissions and fuel consumption was measured under the stoichiometric and lean operating conditions. Due to the mixture distribution controlled by the mixture injection, a large quantity of recirculated exhaust gas could be introduced into the combustion chamber under the stoichiometric air/fuel ratio. The limit of EGR ratio was 48 %.

A model has been developed which predicts engine-out hydrocarbon (HC) emissions for spark-ignition engines. The model consists of a set of scaling laws that describe the individual processes that contribute to HC emissions. The model inputs are the critical engine design and operating variables. This set of individual process scaling relations was then calibrated using production spark-ignition engine data at a fixed light-load operating point. The data base consisted of engine-out HC emissions from two-valve and four-valve engine designs with variations in spark timing, valve timing, coolant temperature, crevice volume, and EGR, for five different engines. The model was calibrated separately for the three different engines to accommodate differences in engine design details and to determine the relative magnitudes of each of the major sources. A good fit to this database was obtained.